Poly[[(methanol)(μ4-2,4,5,6-tetrafluorobenzene-1,3-dicarboxylato)copper(II)] methanol monosolvate]
نویسندگان
چکیده
In the title compound, {[Cu(C(8)F(4)O(4))(CH(3)OH)]·CH(3)OH}(n), two Cu(II) atoms are bridged by four carboxyl-ate groups, forming the well known paddle-wheel secondary building unit (SBU) with axial methanol ligands. In each ligand, the dihedral angles between the benzene ring and the two carboxyl-ate groups are 80.43 (17) and 62.5 (4)°. Within each SBU, the four carboxyl-ate groups come from four symmetry-equivalent tetra-fluoro-isophthalate ligands. Each tetra-fluoro-isophthalate group connects two SBUs, forming a layered structure . In the crystal, O-H⋯O hydrogen bonds involving the free and ligated methanol mol-ecules link the mol-ecules into a three-dimensional supra-molecular network.
منابع مشابه
catena-Poly[[[aqua(di-2-pyridylamine-κ2 N 2,N 2′)manganese(II)]-μ-5-ferrocenylbenzene-1,3-dicarboxylato-κ3 O 1,O 1′:O 3] methanol monosolvate monohydrate]
In the title coordination polymer, {[FeMn(C(5)H(5))(C(13)H(7)O(4))(C(10)H(9)N(3))(H(2)O)]·CH(3)OH·H(2)O}(n), the Mn(II) ion has a distorted octa-hedral coordination geometry and is ligated by two N atoms from two di-2-pyridyl-amine mol-ecules, three O atoms from two 5-ferrocenyl-benzene-1,3-dicarboxyl-ate anions and one O atom from a coordinated water mol-ecule. The Mn-O distances range from 2....
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